I³MS - Lindgren Seminar

Location: AICES Seminar Room 115, 1st floor, Schinkelstr. 2, 52062 Aachen

Dr. Eric Lindgren - Modelling of Electrostatic Self-Assembly in Many-Body Dielectric Systems

AICES Graduate School, RWTH Aachen University


A numerical method based on a Galerkin approximation of an integral equation formulation to compute electrostatic interactions between many dielectric particles will be introduced. The method is sufficiently general, as it is able to treat systems embedded in a homogeneous dielectric medium, containing an arbitrary number of spherical particles of arbitrary size, charge, dielectric constant and position in the three-dimensional space. Simple numerical examples will be presented to illustrate the capabilities of the model, and special focus will be given to the influence of non-additive mutual polarization between particles in an electrostatic interaction. Calculations that successfully reproduce many of the observed patterns of behaviour of two experimental studies relating to electrostatic self-assembly will also be presented. The first study relates to experiments on the assembly of polymer particles that have been subjected to tribocharging, and the second study explores events observed following collisions between single particles and small clusters composed of charged particles derived from a metal oxide composite. Finally, current developments relating to the continuum treatment of ionic species in the medium will be briefly addressed.

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